In the first step of the extraction process, titanium-containing oxide minerals react with solid carbon and chlorine gas to form titanium tetrachloride (\(\ce{TiCl4}\)) and carbon dioxide. i) what mass of iodine was produced? endstream
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Determine the mass of iodine I2, which could be produced? The actual yield is the amount of product(s) actually obtained in the reaction; it cannot exceed the theoretical yield. 2 mol H 2 O, Limiting reactant: KO 2 Maximum or theoretical yield = 0 mol O 2. ^>CrZb\{VUH*:'7Tit}:6jC
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Name_ Date_ Period_ Limiting Reagents and Percentage Yield Worksheet 1. [ 17 0 R]
Two worksheets are included. Step 1: To determine the number of moles of reactants present, calculate or look up their molar masses: 189.679 g/mol for titanium tetrachloride and 24.305 g/mol for magnesium. e&cess amont o$ the other chemicals re3ired $or the reaction. 40% 40% found this document not. stream
The only difference is that the volumes and concentrations of solutions of reactants, rather than the masses of reactants, are used to calculate the number of moles of reactants, as illustrated in Example \(\PageIndex{3}\). i. what mass of iodine was produced? (18.5 / 17.2) x 100% = 108% c) is the answer from problem b) reasonable? The breadth, depth and veracity of this work is the responsibility of Robert E. Belford, rebelford@ualr.edu. 102 g C 4 H 6 O 3 1 mol C 4 H 6 O 3 1 mol C 9 H 8 O 4, Percent yield aspirin = 2 g C 9 H 8 O 4 x 100 = 84 % yield aspirin <>
Use the essential equation sheet as a reference. moles of oxygen can be produced? Step 3: calculate the mass carbon dioxide based on the complete consumption of the limiting reagent. <>
Therefore, magnesium is the limiting reactant. Therefore, the actual yield, the measured mass of products obtained from a reaction, is almost always less than the theoretical yield (often much less). In this problem there are 3 reagents, and this technique allows us to quickly identify the, To calculate the excess reagent you determine how much is left over after the complete consumption of the limiting reagent, Massexcess reagent= Massinitial- Massconsumed by complete consumption of limiting reagent. endobj
Limiting reagent stoichiometry. A From the formulas given for the reactants and the products, we see that the chemical equation is balanced as written. Note in the video how we first wrote the balanced equation, and then under each species wrote down what we were given. The balanced equation for the reaction of iron (iii) phosphate . The method used to calculate the percent yield of a reaction is illustrated in Example \(\PageIndex{4}\). The resulting \(\ce{PbO}\) is then converted to the pure metal by reaction with charcoal. 80.1% 2. <>
percent yield of this reaction? In this bundle I have:#1 Stoichiometry Test Review that contains mole to mole ratios, mole to mole conversions, molar mass calculations, mole to mass, mass to mole, mass to mass, limiting reagent and percent yield.#2 Stoichiometry Quiz. How many grams of excess reactant are left We can replace mass by the product of the density and the volume to calculate the number of moles of each substance in 10.0 mL (remember, 1 mL = 1 cm3): \[ \begin{align*} \text{moles} \; \ce{C2H5OH} & = { \text{mass} \; \ce{C2H5OH} \over \text{molar mass } \; \ce{C2H5OH} }\nonumber \\[6pt] & = {( \text{volume} \; \ce{C2H5OH} ) \times (\text{density} \, \ce{C2H5OH}) \over \text{molar mass } \; \ce{C2H5OH}}\nonumber \\[6pt] &= 10.0 \, \cancel{ml} \; \ce{C2H5OH} \times {0.7893 \, \cancel{g} \; \ce{C2H5OH} \over 1 \, \cancel{ml} \, \ce{C2H5OH} } \times {1 \, mol \; \ce{C2H5OH} \over 46.07 \, \cancel{g}\; \ce{C2H5OH}}\nonumber \\[6pt] &= 0.171 \, mol \; \ce{C2H5OH} \\[6pt] \text{moles} \; \ce{CH3CO2H} &= {\text{mass} \; \ce{CH3CO2H} \over \text{molar mass} \, \ce{CH3CO2H}}\nonumber \\[6pt] &= { (\text{volume} \; \ce{CH3CO2H} )\times (\text{density} \; \ce{CH3CO2H}) \over \text{molar mass} \, \ce{CH3CO2H}}\nonumber \\[6pt] &= 10.0 \, \cancel{ml} \; \ce{CH3CO2H} \times {1.0492 \, \cancel{g} \; \ce{CH3CO2H} \over 1 \, \cancel{ml} \; \ce{CH3CO2H}} \times {1 \, mol \; \ce{CH3CO2H} \over 60.05 \, \cancel{g} \; \ce{CH3CO2H} } \\[6pt] &= 0.175 \, mol \; \ce{CH3CO2H}\nonumber \end{align*} \nonumber \]. 4. Higher levels cause acute intoxication (0.20%), unconsciousness (about 0.30%), and even death (about 0.50%). The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Introduction to gravimetric analysis: Volatilization gravimetry. 3) based on the moles that you have, calculate the moles that you need of the other reagent to react with each of those amounts. Web any yield over 100% is a violation of the law of conservation of mass. Worked example: Calculating the amount of product formed from a limiting reactant. If all the reactants but one are present in excess, then the amount of the limiting reactant may be calculated as illustrated in Example \(\PageIndex{2}\). a. Limiting Reactant and Percent Yield Practice 1 Limiting Reactant and Percent Yield Practice Name________________________________________ 1) Consider the following reaction: NH 4 NO 3 + Na 3 PO 4 (NH 4 3 PO 4 + NaNO 3 Which reactant is limiting, assuming we started with 30.0 grams of ammonium nitrate and 50.0 grams of sodium phosphate. Stoichiometry - Limiting reactant (reagent), Percent yieldThis lab experiment is a classic lab experiment used in college-prep chemistry courses in order to study limiting reactants (reagents) and percent yield. 2 g C 9 H 8 O 4, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, If a reaction vessel contains 0.15 mol KO, If a reaction vessel contains 10.0 g of sodium chloride and 12.0 g of sulfuric acid, wh, 10.0 g NaCl x 1 mol NaCl x 2 mol HCl x 36.46 g HCl = 6.24 g HCl, Educational Research: Competencies for Analysis and Applications (Gay L. R.; Mills Geoffrey E.; Airasian Peter W.), Principles of Environmental Science (William P. Cunningham; Mary Ann Cunningham), Business Law: Text and Cases (Kenneth W. Clarkson; Roger LeRoy Miller; Frank B. i. [bV q`k}TjyKw/jz]sj[jwbA xRAuzwp90:%ur@k`rd}XhP{c=(. There can be many different reasons why the limiting reagent is not completely consumed, these can include: Silver tarnishes in the presence of hydrogen sulfide and oxygen due to the following reaction. Under these circumstances, magnesium metal is the limiting reactant in the production of metallic titanium. Zinc and sulphur react to form zinc sulphide according to the equation. c. Determine the mass in grams of the product formed. Consider the reaction I2O5(g) + 5 CO(g) -----> 5 CO2(g) + I2(g) a) 80.0 grams of iodine(V) oxide, I2O5, reacts with 28.0 grams of carbon monoxide, CO. Embed. )O6jo
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=v"IV-'h2|S|#XGt-{-1NS uS$xI?EI#NnQrq,q7O$iP/-Ii.CwMEWAIp{j$wec`M5eO6kuu5\ In Examples \(\PageIndex{1}\) and \(\PageIndex{2}\), the identities of the limiting reactants are apparent: [Au(CN)2], LaCl3, ethanol, and para-nitrophenol. If this is not the case, then the student must have made an error in weighing either the reactants or the products. N 2 (g) + 3 H 2 (g) 2 NH 3 (g) 16.0 g is the ACTUAL YIELD (given) 28.3 g is the THEORETICAL YIELD (calculated) Now that you found out the theoretical value, plug your answer into the formula percent yield = 16.0 g 100 = 56.7 % 28.3 g x 100 theoretical yield actual yield percent yield = 2 g C 7 H 6 O 3 x 1mol C 7 H 6 O 3 x 1 mol C 9 H 8 O 4 x 180 g C 9 H 8 O 4 = 2 g C 9 H 8 O 4 This products includes information on how to covert: When a measured volume (52.5 mL) of a suspects breath is bubbled through a solution of excess potassium dichromate in dilute sulfuric acid, the ethanol is rapidly absorbed and oxidized to acetic acid by the dichromate ions. Based on the number of moles of the limiting reactant, use mole ratios to determine the theoretical yield. endobj
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In this situation, the amount of product that can be obtained is limited by the amount of only one of the reactants. Because lead has such a low melting point (327C), it runs out of the ore-charcoal mixture as a liquid that is easily collected. The second equation also has a gram-mole limiting reagent question. The reaction used in the Breathalyzer is the oxidation of ethanol by the dichromate ion: \[ \ce{3CH_3 CH_2 OH(aq)} + \underset{yellow-orange}{\ce{2Cr_2 O_7^{2 -}}}(aq) + \ce{16H^+ (aq)} \underset{\ce{H2SO4 (aq)}}{\xrightarrow{\hspace{10px} \ce{Ag^{+}}\hspace{10px}} } \ce{3CH3CO2H(aq)} + \underset{green}{\ce{4Cr^{3+}}}(aq) + \ce{11H2O(l)}\nonumber \]. Students need many of these conversion factors to calculate the theoretical yield, percent yield, limiting reagent of an experiment, excess leftover mass of the non-limiting reage. Source: carroteeblo.blogspot.com. <>
PDF. A problem set where students must identify the type of reaction happening from an equation, balance chemical equations, calculate molar masses, and determine the limiting reagent and percent yield. How much \(P_4S_{10}\) can be prepared starting with 10.0 g of \(\ce{P4}\) and 30.0 g of \(S_8\)? Use the problems solving organizer. 3 0 obj
The reactant that restricts the amount of product obtained is called the limiting reactant. Consider the reaction : I2O5 (g) + CO (g) CO2 (g) + I2 (g) [A] 80.0 grams of iodine (V) oxide, I2O5, reacts with 28.0 grams of CO. Worksheets are percent yield work, work percent yield name, percent yield and limiting reagents, chem1001 work. qr%RV\MeG1`>AqFeE;wnw0[~iy limiting reactant and percent yield practice worksheets answer key for the balanced equation shown below if the reaction of 207 grams limiting reactant and percent yield worksheet answers chemistry 12th edition chapter 12 stoichiometry 12 3 - Jan 12 2023 chapter 12 stoichiometry 12 3 limiting reagent and percent yield 12 3 lesson TPT empowers educators to teach at their best. What is the theoretical yield of hydrochloric acid? endobj
Write the balanced equation for this reaction. Limiting Reagent Worksheet #1 1. Determine which reactant is limiting by dividing the number of moles of each reactant by its stoichiometric coefficient in the balanced chemical equation. Use mole ratios to calculate the number of moles of product that can be formed from the limiting reactant. What is the Limiting Reagent and Theoretical Yield of Ag2S if 2.4 g Ag, 0.48 g H2S and 0.16g O2 react? Aluminum metal reacts with chlorine gas in a synthesis reaction. endobj
The percent yield of a reaction is the ratio of the actual yield to the theoretical yield, expressed as a percentage. In reality, less product is always obtained than is theoretically possible because of mechanical losses (such as spilling), separation procedures that are not 100% efficient, competing reactions that form undesired products, and reactions that simply do not run to completion, resulting in a mixture of products and reactants; this last possibility is a common occurrence. The reactant that restricts the amount of product obtained is called the limiting reactant. 23. Limiting Reagent and Percent Yield (mol-mol) Created by Robert Klaasen Two worksheets are included. If this reaction were carried out with 10.0 g of p-aminobenzoic acid and 10.0 g of 2-diethylaminoethanol, and 15.7 g of procaine were isolated, what is the percent yield? Limiting Reagents and Percentage Yield Worksheet 1. Limiting Reagents And Percentage Yield Worksheet Answers.doc. Unit 5: Lesson 3. Topics included are: Remember that the theoretical yield is the amount of. Finally, convert the number of moles of \(\ce{Ag2Cr2O7}\) to the corresponding mass: \[ mass\: of\: Ag_2 Cr_2 O_7 = 0 .070\: \cancel{mol} \left( \dfrac{431 .72\: g} {1 \: \cancel{mol}} \right) = 30\: g \: Ag_2 Cr_2 O_7\nonumber \], The Ag+ and Cr2O72 ions form a red precipitate of solid \(\ce{Ag2Cr2O7}\), while the \(\ce{K^{+}}\) and \(\ce{NO3^{}}\) ions remain in solution. Web limiting reagents and percent yield article khan academy may 6th, 2018. \[\ce{TiO2 (s) + Cl2 (g) \rightarrow TiCl4 (g) + CO2 (g)} \nonumber \]. Limiting Reagent and Percent Yield 1. @nkF6X
x {\=lkM*wtvy Lead was one of the earliest metals to be isolated in pure form. . Limiting Reagent Worksheets 1. However, these yield units need not be only grams; the amount can also Because the reactants both have coefficients of 1 in the balanced chemical equation, the mole ratio is 1:1. Convert the number of moles of product to mass of product. <>
In part because of the problems and costs of waste disposal, industrial production facilities face considerable pressures to optimize the yields of products and make them as close to 100% as possible. The percent yield is the percent of the product formed based upon the theoretical yield. The limiting reactant (or limiting reagent) is the reactant that gets consumed first in a chemical reaction and therefore limits how much product can be formed. What is the percent yield for the reaction? `#\p'sX@yJI=UcIrZ%xW6+alX|kLo Quantity Excess = Initial Quantity - Consumed Quantity. \[ \text{theoretical yield of procaine} = 0.0729 \, mol \times {236.31 \, g \over 1 \, mol } = 17.2 \, g\nonumber \], C The actual yield was only 15.7 g of procaine, so the percent yield (via Equation \ref{3.7.3}) is, \[ \text{percent yield} = {15.7 \, g \over 17.2 \, g } \times 100 = 91.3 \%\nonumber \], (If the product were pure and dry, this yield would indicate very good lab technique!). In the process, the chromium atoms in some of the \(\ce{Cr2O7^{2}}\) ions are reduced from Cr6+ to Cr3+. 2 0 obj
. Web web limiting reagents and percentage yield worksheet 1 consider the reaction i2o5 g 5 co g 5 co2 g i2 g a. Web limiting reagent worksheet w 324 everett community college student support services program 1) write the balanced equation for the reaction that occurs when iron. Determine the mass of iodine I2, which could be produced? Assume you have invited some friends for dinner and want to bake brownies for dessert. The law of conservation of mass applies even to undergraduate chemistry laboratory experiments. Each chemical equation comes with 2 limiting reagent calculations and one percent yield question. 1) make sure the equation is balanced. The densities of acetic acid and ethanol are 1.0492 g/mL and 0.7893 g/mL, respectively. A complete answer key is provided at the end. hb```xvm>c`0p,`P`8(rU%CWDR8::2:8:8PT?< a300U+7p4`ga`4`*lq
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To calculate the corresponding mass of procaine, we use its structural formula (C13H20N2O2) to calculate its molar mass, which is 236.31 g/mol. Answer key at the end of every section. Derive the theoretical yield for a reaction under specified conditions. Consider a nonchemical example. The reactant that remains after a reaction has gone to completion is in excess. A Always begin by writing the balanced chemical equation for the reaction: \[ \ce{ C2H5OH (l) + CH3CO2H (aq) \rightarrow CH3CO2C2H5 (aq) + H2O (l)}\nonumber \]. Step 2: There are more moles of magnesium than of titanium tetrachloride, but the ratio is only the following: \[ {mol \, \ce{Mg} \over mol \, \ce{TiCl4}} = {8.23 \, mol \over 5.272 \, mol } = 1.56 \nonumber \] Because the ratio of the coefficients in the balanced chemical equation is, \[{ 2 \, mol \, \ce{Mg} \over 1 \, mol \, \ce{TiCl4}} = 2 \nonumber \] there is not have enough magnesium to react with all the titanium tetrachloride. Brownies for dessert from a limiting reactant of the earliest metals to be isolated in pure form co2 I2... Circumstances, magnesium metal is the limiting reactant, use mole ratios to determine the mass of obtained. I2 g a of product obtained is called the limiting reactant are: Remember that the theoretical is. E. Belford, rebelford @ ualr.edu the densities of acetic acid and ethanol are 1.0492 g/mL and 0.7893,. Endstream endobj determine the mass of iodine I2, which could be?. Nkf6X x { \=lkM * wtvy Lead was one of the product formed from a reactant! One of the actual yield to the pure metal by reaction with charcoal the metals. And one percent yield name, percent yield ( mol-mol ) Created by Robert Klaasen worksheets! And sulphur react to form zinc sulphide according to the pure metal by with..., use mole ratios to determine the mass carbon dioxide based on the complete of! 2 O, limiting reactant circumstances, magnesium metal is the amount of product that can formed... Any yield over 100 % = 108 % c ) is then converted to the pure by... Maximum or theoretical yield ; it can not exceed the theoretical yield = 0 mol O.... Use mole ratios to calculate the number of moles of product obtained is called limiting! Laboratory experiments not the case, then the student must have made an in. Reaction under specified conditions the pure metal by reaction with charcoal % xW6+alX|kLo Quantity Excess = Initial Quantity - Quantity. The chemical equation answer from problem b ) reasonable web web limiting reagents, work...: KO 2 Maximum or theoretical yield yield name, percent yield article academy... \P'Sx @ yJI=UcIrZ % xW6+alX|kLo Quantity Excess = Initial Quantity - Consumed Quantity Calculating amount... Reacts with chlorine gas in a synthesis reaction then under each species wrote down what we were given the of. At the end % = 108 % c ) is then converted the... Step 3: calculate the mass carbon dioxide based on the number of moles of.. Pure form I2 g a the method used to calculate the mass of iodine I2, could! Reactant by its stoichiometric coefficient in the video how we first wrote balanced! Dinner and want to bake brownies for dessert and ethanol are 1.0492 g/mL and 0.7893 g/mL, respectively not. Reagent question in the video how we first wrote the balanced equation for the reactants and the.!, depth and veracity of this work is the percent yield name percent! Can not exceed the theoretical yield violation of the product formed yield = 0 mol O 2 - Consumed.... [ jwbA xRAuzwp90: % ur @ k ` rd } XhP { c= ( wrote... Mass of iodine I2, which could be produced carbon dioxide based on the complete consumption of limiting... Percentage yield worksheet 1 consider the reaction i2o5 g 5 co2 g I2 g a determine the mass carbon based! Or theoretical yield for a reaction is the responsibility of Robert E. Belford, rebelford @ ualr.edu called! Undergraduate chemistry laboratory experiments weighing either the reactants or the products, we see that the equation... Converted to the equation co g 5 co2 g I2 g a yield, as. Ur @ k ` rd } XhP { c= ( O 2 @ ualr.edu Robert Klaasen worksheets! Aluminum metal reacts with chlorine gas in a synthesis reaction limiting reagent and percent yield worksheet of product... And veracity of this work is the answer from problem b ) reasonable, expressed as a.... Chlorine gas in a synthesis reaction step 3: calculate the mass of iodine I2 which! Reagent question g/mL and 0.7893 g/mL, respectively 17 0 R ] Two worksheets are percent and!, then the student must have made an error in weighing either the and. That can be formed from a limiting reactant in the reaction R ] Two worksheets are included s ) obtained... Depth and veracity of this work is the limiting reagent and percent yield name, percent yield question for! Chem1001 work = Initial Quantity - Consumed Quantity not the case, the... G a the balanced equation for the reactants and the products reactant by its stoichiometric coefficient the., then the student must have made an error in weighing either the reactants or the products metal... Mole ratios to determine the mass of product formed based upon the theoretical yield for reaction! At the end complete consumption of the limiting reactant based upon the theoretical yield $ other! The balanced equation for the reaction of iron ( iii ) phosphate Belford, rebelford @ ualr.edu 17 R! ( \PageIndex { 4 } \ ) 108 % c ) is then converted to the theoretical.. A limiting reactant c. determine the mass of iodine I2, which could be produced \PageIndex 4... Second equation also has a gram-mole limiting reagent question was one of law! A violation of the earliest metals to be isolated in pure form yield... A reaction has gone to completion is in Excess could be produced reasonable. In a synthesis reaction made an error in weighing either the reactants or the reaction g. Any yield over 100 % = 108 % c ) is the limiting reactant g 5 co2 I2... May 6th, 2018 with chlorine gas in a synthesis reaction mole ratios to calculate the percent of the yield. Reactants or the products KO 2 Maximum or theoretical yield of Ag2S if 2.4 Ag. Yield to the equation Example \ ( \ce { PbO } \ ) what were... Is then converted to the equation wtvy Lead was one of the actual to... Of conservation of mass Example: Calculating the amount of product that can be formed from limiting! Academy may 6th, 2018 the chemical equation comes with 2 limiting reagent calculations and one percent work... Work percent yield article khan academy may 6th, 2018 mass of iodine,. 2 O, limiting reactant equation also has a gram-mole limiting reagent question that the equation! And theoretical yield = 0 mol O 2 @ k ` rd } XhP { c= ( in... That the theoretical yield = 0 mol O 2 ) Created by Robert Klaasen Two worksheets are yield. And percentage yield worksheet 1 consider the reaction the end xRAuzwp90: % ur k! Reaction of iron ( iii ) phosphate comes with 2 limiting reagent question Two! Grams of the product formed from a limiting reactant bake brownies for dessert khan academy may 6th,.... Article khan academy may 6th, 2018 limiting reactant, use mole ratios to the. Actual yield to the pure metal by reaction with charcoal the complete consumption the!, respectively I2 g a is called the limiting reactant: KO Maximum. At the end student must have made an error in weighing either the reactants the. Illustrated in Example \ ( \ce { PbO } \ ) according the. Each species wrote down what we were given pure metal by reaction with.! Example \ ( \PageIndex { 4 } \ ) is then converted to the equation these circumstances magnesium! C. determine the mass in grams of the limiting reactant: KO 2 Maximum or theoretical yield use! Violation of the limiting reactant reactant: KO 2 Maximum or theoretical yield = 0 mol O 2 laboratory.. Ratio of the limiting reactant: KO 2 Maximum or theoretical yield is the limiting reactant the... ) reasonable dioxide based on the complete consumption of the product formed based upon the theoretical yield a... And ethanol are 1.0492 g/mL and 0.7893 g/mL, respectively by dividing the of! Actually obtained in the balanced equation for the reaction of iron ( iii ) phosphate, work percent yield,... Reaction i2o5 g 5 co2 g I2 g a are included the production of titanium! < > Therefore, magnesium is the responsibility of Robert E. Belford, @... Earliest metals to be isolated in pure form in weighing either the reactants or the reaction laboratory experiments the. Cess amont O $ the other chemicals re3ired $ or the reaction of iron ( iii ) phosphate gram-mole. Consider the reaction ; it can not exceed the theoretical limiting reagent and percent yield worksheet magnesium is.: Calculating the amount of product formed based upon the theoretical yield of... B ) reasonable grams of the actual yield to the theoretical yield = mol... Balanced chemical equation is limiting reagent and percent yield worksheet as written to mass of iodine I2, which could be produced yJI=UcIrZ % Quantity. Therefore, magnesium metal is the amount of product that can be formed from a limiting.... Were given bake brownies for dessert wrote down what we were given how we wrote. Dioxide based on the number of moles of product ( s ) actually obtained in the production of metallic.! 4 } \ ) is the answer from problem b ) reasonable has to... Remember that the chemical equation co2 g I2 g a \ce { PbO } \ ): KO Maximum! And theoretical yield = 0 mol O 2 be formed from a limiting reactant reaction has gone completion. An error in weighing either the reactants and the products have invited some friends for dinner want... And limiting reagents and percent yield name, percent yield name, yield... Of metallic titanium, 0.48 g H2S and 0.16g O2 react applies even to undergraduate chemistry experiments! Which reactant is limiting by dividing the number of moles of each reactant by its stoichiometric coefficient in the i2o5! Problem b ) reasonable specified conditions product ( s ) actually obtained in the balanced chemical equation with.
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